I apologise if this is TMI but lithium batteries are clearly confusing.
All lithium rechargables are lithium ion. Marketing confuses things. Cylindrical cells are called lithium ion. Pouch cells lipos. Chemistry is very similar, pouch cells have a paste, cylindricals have a liquid.
Pouch cells puff, cylindricals vent and are less likely to be damaged when it happens.
Storage charges are useful, but so long as the cell isn't full or empty (30% SOC either way is good) all should be well. This also applies to cylindrical cells, I can't imagine that titan think differently. This voltage is 3.7v for lithium's that aren't life cells.
Storing any lithium battery empty is really bad for it's longevity and safety.
Titan batteries have the same chemistry as other batteries. They are still damaged by over or under charge and high discharge currents and catch fire.
Metal cells are resilient and difficult to damage.
Lithium iron phosphate (life) are the only resilient and safe lithium battery, tolerant to overcharge and need to reach 270C to make fire.
They hold less charge but have a very long life. I have some that are 10 next year.
3S batteries are 9.9v.
If you look after lipos (pouch cells) they will last a reasonable amount of time, but they are fragile.
Cylindrical cells are physically robust, won't get stuck in a gun, but other wise have the same issues as pouch cells.
Other than life cells all the others suffer thermal runaway at pretty low temps so if they get hot (from 80C to 130C), they get hotter until fire. Careful charging and use can avoid the cells getting hot.