Sacarathe
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After I've safely discharged the bad LiPo, can I just chuck it in the bin, if so, recycling or landfill?
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If you have a lipo battery tester, make 100% sure that all cells are at 0%, if you have a 7.4v then both cells should be at zero etc.. cut the main lead connector off, wrap the leads together, and it should be safe to chuck in the bin. If you not sure then maybe take it to a local dump for disposal.
better still, drive a nail through the battery, and stand back, LOL (not recommended) I've had a lipo go in one of my rc helicopters, it's not a nice experience!